Technical Guide9 min read

Polyacrylamide Specifications Table

Compare APAM, CPAM and NPAM specification fields, example purchase windows and test methods. Read charge, molecular weight, solids and residual monomer correctly.

Use this reference to compare specification fields across anionic, cationic and nonionic dry PAM, read a supplier TDS and prepare a purchase brief. It is a parameter lookup; product availability, batch acceptance and quotation remain grade-specific.

Tables 1–2 show example purchase windows and screening candidates, not universal limits or ChinaPAM model specifications. Use the quoted grade TDS and batch COA for binding values. Charge examples below use a declared molar basis; other percentages are by mass of supplied product. Do not substitute mol%, wt% or meq/g for one another.

Table 1. Example specification windows by ionic type (dry powder)
ParameterAnionic PAM (APAM): exampleCationic PAM (CPAM): exampleNonionic PAM (NPAM): exampleMethod / conditions to confirm
AppearanceWhite granular powderWhite to off-white granular powderWhite granular powderVisual
Charge typeNegative (carboxylate)Positive (cationic groups; exact chemistry is grade-specific)Nonionic; verify any residual hydrolysis stated for the grade—
Charge density / hydrolysis (declared molar basis)5 – 40%5 – 80%0 – 5%Specify mol% of charged repeat units and the supplier method; hydrolysis is reported only where applicable. A measured meq/g value needs its own mass basis and conversion.
Molecular weight6 – 28 million Da6 – 20 million Da8 – 15 million DaIdentify the MW average and method. For viscosity-based MW, state polymer, solvent, salt concentration, temperature and the applicable correlation.
Solid contentIllustrative minimum: ≥88% or ≥90%; select one agreed limitIllustrative minimum: ≥88% or ≥90%; select one agreed limitIllustrative minimum: ≥88% or ≥90%; select one agreed limitDeclared solids/moisture method; 105 °C is an example only if that method uses it
Residual acrylamideExample purchase limits: ≤0.05%, or ≤0.025% where specifically agreed for the intended useExample purchase limits: ≤0.05%, or ≤0.025% where specifically agreed for the intended useExample purchase limit: ≤0.05%State residual acrylamide as mass fraction of supplied product and the validated method; match the grade and intended use.
Example dissolution-test window (0.1% product, 20–40 °C)30 – 90 min by MW45 – 90 min60 – 90 minStated concentration, water quality, temperature and mixing conditions
Water insolubles≤ 0.3%≤ 0.3%≤ 0.5%Define solution concentration, filter medium, drying basis and result denominator.
Bulk density0.60 – 0.85 g/cm³0.60 – 0.85 g/cm³0.60 – 0.85 g/cm³Specify loose bulk density and its method; tapped density is a separate result. EN 1407 gives 0.5–0.9 g/cm³ as typical only for the anionic/nonionic products in its scope [3].
Particle size≥ 90% between 0.2 – 1.6 mm≥ 90% between 0.2 – 1.6 mm≥ 90% between 0.2 – 1.6 mmDefine sieve apertures, retained mass basis and sample condition.
pH (0.1% solution)6 – 83 – 66 – 8Measure at the stated product concentration, water composition and temperature.
Example application-test pH envelope4 – 121 – 101 – 10Qualify at the actual process pH; test the intended endpoints and polymer stability.
Shelf life / storage conditions24 months in the manufacturer dry-polymer example [1]; grade storage conditions control24 months in the manufacturer dry-polymer example [1]; grade storage conditions control24 months in the manufacturer dry-polymer example [1]; grade storage conditions controlKeep sealed and dry. Below 35 °C is an illustrative storage limit; the grade TDS must confirm the conditions for its stated shelf life.

A manufacturer example shows why conditions matter: MT Aqua Polymer lists 13 million Da for nonionic N-100S and 16 million Da for anionic A-110L. Both list a bulk-specific-gravity reference value of 0.65 ± 0.10. Their 0.1% solution-pH references are 5–7 and 6–8 respectively. The list separately states 0.1% solution viscosity at 25 °C and identifies the physical-property figures as reference values [5]. These are that manufacturer’s reference values, not ChinaPAM grade specifications.

Table 2. Example charge/MW combinations to include in a trial plan
Ionic typeCharge / hydrolysis example (mol%)Molecular weightApplication to investigate; confirm by test
Anionic5 – 15% (low)15 – 20 M (high)Sand washing, aggregate wash water, stone-cutting slurry
Anionic15 – 30% (medium)15 – 20 MMineral tailings thickening, coal preparation, municipal primary clarification
Anionic25 – 40% (high)6 – 15 MIndustrial effluent after hydroxide precipitation
Anionic20 – 30%25 – 28 M (ultra-high)Fine tailings, TBM and bentonite slurry, red mud
Anionic (PHPA / HPAM)25 – 35%15 – 25 MDrilling fluid encapsulation and viscosity, EOR polymer flooding
Cationic5 – 20% (lower-charge example)8 – 12 MPaper retention and drainage, low-organic sludge
Cationic20 – 40% (mid-charge example)8 – 12 MMunicipal mixed sludge on belt presses and filter presses
Cationic40 – 60% (higher-charge example)10 – 12 MWaste activated sludge, food and paper mill sludge
Cationic60 – 80% (high to very high)11 – 14 MDigested sludge, oily and fat-rich sludge, centrifuges and screw presses
Nonionic< 5%8 – 15 MAcidic mine water, low-pH tailings, high-salinity water

How to read a polyacrylamide specification sheet

Start with ionic type, charge or hydrolysis basis, molecular weight or intrinsic viscosity, solids or active-polymer content, and residual monomer. These fields help shortlist candidates, but application tests determine whether a grade meets the process target. Read MW together with charge, polymer structure, preparation and the solids-separation equipment.

Solids and active-polymer content are different quantities unless the product documentation establishes otherwise. If 90% and 80% are both confirmed active-polymer mass fractions, 0.90 ÷ 0.80 − 1 = 12.5% more active polymer per kilogram of product. This calculation cannot be inferred from solids content alone. Residual-monomer requirements depend on the actual grade, destination, use and dose.

For U.S. public drinking-water systems, 40 CFR 141.111 controls the combination of residual monomer and polymer dose: 0.05% residual acrylamide dosed at 1 ppm, or an equivalent combination [4]. This is not a stand-alone food-use limit. Check the exact product approval and maximum use level for the intended project.

Molecular weight vs. intrinsic viscosity

Suppliers may infer molecular weight from intrinsic viscosity using a stated Mark–Houwink relationship. The polymer, solvent, temperature and constants must match the measurement [2]. Ask for the reported method and conditions before comparing two quoted MW figures; do not assume one universal 1 mol/L NaCl at 30 °C conversion for every PAM grade.

Writing a purchase specification

Name the ionic type and the required charge window with its basis, the MW or viscosity requirement with its method, and the agreed solids/active content, residual monomer, dissolution and insolubles requirements. A purchase window such as cationic 40 ± 5%, solids ≥89% and insolubles ≤0.3% is an illustrative brief, not a specification for all PAM. Lock the actual values with the selected grade and test protocol.

  • Ionic type and charge window, with the charge basis
  • MW or intrinsic-viscosity requirement, method and conditions
  • Solids or active polymer, residual monomer, insolubles and dissolution acceptance requirements
  • Packaging, for example 25 kg bags or bulk bags as quoted, plus shelf life and documented storage conditions
  • Grade TDS, batch COA, SDS and any use-specific approval documents

Use the RFQ specification template for the complete process, acceptance and commercial brief, and the COA, TDS and SDS review for document and batch checks. For process-duty screening, use the flocculant selection chart.

Anionic Brand Equivalents by Charge and Molecular Weight

The tables above show illustrative specification and purchase-review windows. If you are matching a named anionic grade, the pages below explain how we screen an equivalent for each one. Ask us to review the required grade identity, application and documentation before quotation.

Very low charge

Low charge

AN 900 series

High charge

Not sure which grade you need? Send us your current product name and application and we will suggest a screening route.

Frequently Asked Questions

What is the standard solid content of polyacrylamide powder?

The table illustrates alternative powder-solids minimum requirements of 88% or 90%; the buyer must choose the actual grade limit. Manufacturer reference [1] describes about 90% active dry polymer and 25–50% active emulsion in its stated context. Confirm whether a supplier’s figure is solids or active polymer and whether it is a minimum, range or typical value.

What residual acrylamide level is acceptable?

Agree the limit for the actual grade, destination and intended use. The ≤0.05% and ≤0.025% figures shown are illustrative purchase-review limits; they do not establish regulatory permission, food-contact suitability or a certification claim.

Does higher molecular weight always mean better flocculation?

No. Higher MW can increase bridging within a comparable polymer system, but dissolution and shear response also depend on the grade and preparation. Compare charge, structure, feed chemistry and equipment in a defined application test rather than choosing the highest MW alone.

[1] Kemira Water Handbook (2020), stated polymer examples · [2] Malvern Panalytical, Mark–Houwink conditions

[3] EN 1407:2023 public preview, scope and physical properties · [4] 40 CFR 141.111, acrylamide dose/monomer treatment technique

Data note: numeric purchase windows and trial combinations are author-selected examples, not a ChinaPAM model TDS or guaranteed application result. The cited manufacturer and standard references support the stated concepts and scoped examples. Grade TDS, batch COA and SDS are available on request.

[5] MT Aqua Polymer, powder-product reference list and test conditions

Explore Product Grades

PAM

Polyacrylamide (All Grades)

Full APAM, CPAM, NPAM and PHPA range with order-specific pricing and available documents confirmed for the selected grade.

APAM

Anionic Polyacrylamide (APAM)

High and medium molecular weight APAM for wastewater clarification and mining tailings.

CPAM

Cationic Polyacrylamide (CPAM)

High and medium charge density CPAM for sludge dewatering and paper retention.

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